Off-line optimization and control for real time integration of a three-phase hydrogenation catalytic reactor

In order to develop and test the integration procedure, in this paper a real time process integration involving the optimization and control of the process is presented, in this case, with the two-layer approach. The used optimization algorithms were Levenberg–Marquardt and SQP that solve a non-linear least square problem subject to bounds on the variables. The two-layer approach is a hierarchical control structure where an optimization layer calculates the set points and manipulated variables to the advanced controller, which is based on the dynamic matrix control with constraints (QDMC). The non-isothermal dynamic model of the three-phase slurry catalytic reactor with appropriate solution procedure was utilized in this work (Vasco de Toledo, E. C., Santana, P. L., Maciel, M. R. W., & Maciel Filho, R. (2001). Dynamic modeling of a three-phase catalytic slurry reactor. Chemical Engineering Science, 56, 6055–6061). The model consists on mass and heat balance equations for the catalyst particles as well as for the bulk phases of gas and liquid. The model was used to describe the dynamic behavior of hydrogenation reaction of o-cresol to obtain 2-methil-cyclohexanol, in the presence of a catalyst Ni/SiO₂.     

Thermal deformation analysis of tabbed solar cells using solder alloy and conductive film

Finite element analysis (FEA) has been carried out with the aim of understanding the thermal deformation characteristics of two solar cell configurations. One of the solar cell models is tabbed by lead-free solder, the other model by Conductive film (CF). A high temperature soldering process could weaken the bond and reduce the reliability of the cells because of the residual stress caused by the different thermal expansion coefficients of the materials. Moreover, solar irradiation generates temperature distribution across the surface of the solar cell, and the development of solar cells made of thinner crystalline silicon wafers will lead to the reduction in manufacturing costs. In this study, Finite element analysis (FEA) of the manufacturing process has been carried out using both solder and CF bonding. Three temperature cycles were applied to analyze different environmental operating conditions and understand how thermal cycles affect the residual stress during actual service conditions. This investigation provides a comparison of thermal deformations between solder and CF bonded solar cells in order to understand which offers substantial reliability in the long term. Also this study explores the effects of various thicknesses of the silicon wafer on the residual stress and deformation of the solar cells.     

云环境下基于本体的用户行为分析引擎研究

针对当前大型互联网站提升用户体验的需求,本研究创造性地提出基于本体的用户行为分析引擎的思想,它通过上下文感知技术,实时获取用户访问页面时的上下文信息(以下也称为动态行为),基于本体对用户行为建模,建立基于规则的上下文推理算法,对监测到的动态用户行为进行实时推理,及时反馈结果信息给用户。实验表明:本研究理论上独辟蹊径,设计实现上结合了云存储技术,能够一定程度改善用户体验效果。     

Resilience-aware design of interconnected supply chain networks with application to water-energy nexus

The effects of natural disasters, pandemic-induced lockdowns, and other disruptions often cascade across networks. In this work, we use minimum cost of resilience (MCOR) and operation-based resilience metrics to quantify network performance against single-connectivity failures and identify critical connections in interconnected networks. MCOR corresponds to the minimum additional infrastructure investment that is required to achieve a certain level of resilience. To guarantee MCOR, we incorporate the metrics in a multi-scenario mixed-integer linear program (MILP) that accounts for resilience in the design phase of interconnected networks. The goal is to obtain optimal generation and transportation capacities with flexible operation under all single-connectivity disruption scenarios. We demonstrate the applicability of our resilience-aware framework on a water-energy nexus (WEN) example focusing on grass-root design and retrofitting. We further apply the framework to analyze a regional WEN and observe that it is possible to achieve “full” resilience in the expense of additional regional investments.     

Surface Modification of Ready-to-Use Hollow Fiber Ultrafiltration Modules for Oil/Water Separation

Reusing wastewater from oil-related industries is becoming increasingly important, especially in water-stressed oil-producing countries. Before oily wastewater can be discharged or reused, it must be properly treated, e.g., by membrane-based processes like ultrafiltration. A major issue of the applied membranes is their high fouling propensity. This paper reports on mitigating fouling inside ready-to-use ultrafiltration hollow-fiber modules used in a polishing step in oil/water separation. For this purpose, in-situ polyzwitterionic hydrogel coating was applied. The membrane performance was tested with oil nano-emulsions using a mini-plant system. The main factors influencing fouling were systematically investigated using statistical design of experiments.     

UV-shielding by a polyurethane/f-Oil fly ash-CeO2 protective coating

A waste material called oil fly ash (OFA) was acid-functionalized, yielding f-OFA-COOH, which was then reacted with cerium oxide (CeO₂) to make CeO₂-functionalized OFA, or f-OFA-CeO₂. Pristine OFA and f-OFA-CeO₂ were used to make waterborne polyurethane (WBPU) dispersions, referred to as WBPU/OFA and WBPU/f-OFA-CeO₂, respectively, with defined OFA and f-OFA-CeO₂ content. All the dispersions were applied to mild steel as organic coatings to evaluate their protective properties, such as their hydrophobicity, adhesive strength and UV-shielding resistance. These protective properties varied based on the OFA and f-OFA-CeO₂ content. The highest water contact angle, minimum water swelling and maximum adhesive strength were found using WBPU/f-OFA-CeO₂-20 coating (using 2.00 wt% f-OFA-CeO₂), which also showed the maximum ultraviolet (UV) absorption via UV–vis spectroscopy analysis. This UV shielding result also matched field test results, as that coating was found to exhibit the lowest UV degradation near a marine atmosphere, as shown by X-ray photoelectron spectroscopy (XPS) analysis. The least affected hydrophobicity was also recorded for the sample with the WBPU/f-OFA-CeO₂-20 coating.     

Investigation of Creep Feed Grinding Parameters and Heat treatment Effects on the Nickel-base Superalloys

The Nickel base Superalloys are the most famous complicated and useable of Superalloys to make hot zone components of the gas turbines. The complicated dimensional tolerances, specially at the root of the blade show importance of grinding processes at the production of blades root. The prediction of the effect of machining parameters on the soundness of component surface strengthening for reaching to a suitable surface finishing and avoiding from crack formation at the work part during machining operation often is not easy and feasible so needs to more industrial investigation.This research is about frame 5 blade designed by GE and made from Superalloy IN738LC has been investigated. The formation of a plastically deformed and heat affected zone during grinding of Superalloy IN738LC with a high depth of cut but slow work speed (creep feed grinding) was investigated. Parameters such as work speed, depth of cut and radial dressing speed have been considered as variables and their effects have been studied. During experimental performed, the voltage and current of motor measured and power and special energy calculated.Some samples heat-treated (of the 1176℃ for 1 hr under neutral argon gas and cooling rate of 15℃/min up to 537℃ and then air cooling) to study grains recrystallization. Other samples have been created from the roots of blades and then coated by Nickel to measure boundary layer micro-hardness. The results show that increasing work speed leads to increasing the use power. Increasing the depth of cut, by increasing material removal rate, and the radial dressing speed, by decreasing power, lead to decreasing special energy. The temperature created by grinding lead to decreasing plastic deformation and boundary layer formation. When the radial dressing speed changes from 1 to 0.6μm/rev and other parameters are kept unchanged the roughness of surface increases and the special energy decreases. Sufficient dressing is very essential in limiting the width of the molten zone to few micrometers. As a result, it was found that local melting at contact spots to be a rather common mechanism during grinding of superalloys, lead to so-called white layers which can easily be observed on metallographic cross sections.     

An investigation of chloride-substituted Schiff bases as corrosion inhibitors for steel

Polarization and impedance measurements were performed on steel in deaerated 5% HCl solution with and without Schiff base additives within the concentration range 1 × 10⁻⁴–5 × 10⁻³ mol/dm³. The Schiff base compounds used were salicylaldimine, R, N-(2-chlorophenyl)salicyaldimine, 2Cl-R, N-(3-chlorophenyl)salicyaldimine, 3Cl-R, and N-(4-chlorophenyl)salicyaldimine, 4Cl-R. It was found that when the concentration of the inhibitors were increased the inhibitor efficiencies, η, also increased with increasing surface coverage. The results indicated that the ortho-substituted (2Cl-R) compound had the highest inhibition efficiency. All the Schiff base additives studied obeyed the Langmuir isotherm.     

Modified particle swarm optimization and fuzzy regularization for pseudo de-convolution of spatially variant blurs

We propose a modified particle swarm optimization (MPSO) based method for Pseudo De-convolution of the ill-posed inverse problem namely, the space-variant image degradation (SVD). In this paper, SVD is simulated by the pseudo convolution of different sub-regions of the image with different known blurring kernels and additive random noise with unknown variance. Two heuristic modifications are proposed in PSO: 1) Initialization of the swarm and 2) Mutation of the global best. Fuzzy logic is applied for the computation of regularization parameter (RP) to cater for the sensitivity of the problem. The computation of RP is crucial due to the additive noise in the SVD image. Thus mathematical morphology (MM) is applied for better extraction of spatial activity from the distorted image. The performance of the proposed method is evaluated with different test images and noise powers. Comparative analysis demonstrates the superiority of proposed restoration, in terms of quantitative measures, over well-known existing and state-of-the-art SVD approaches.     

Voiced/non-voiced speech classification using adaptive thresholding with bivariate EMD

This paper introduces a robust voiced/non-voiced (VnV) speech classification method using bivariate empirical mode decomposition (bEMD). Fractional Gaussian noise (fGn) is employed as the reference signal to derive a data adaptive threshold for VnV discrimination. The analyzing speech signal and fGn are combined to generate a complex signal which is decomposed into a finite number of complex-valued intrinsic mode functions (IMFs) by using bEMD. The real and imaginary parts of the IMFs represent the IMFs of observed speech and fGn, respectively. The log-energies of both types of IMFs are calculated. There exist similarities between the IMF log-energy representation of fGn and unvoiced speech signals. Hence, the upper confidence limit from IMF log-energies of fGn is used as data adaptive threshold for VnV classification. If the subband log-energy of speech segment exceeds the threshold, the segment is classified as voiced and unvoiced otherwise. The experimental results show that the proposed algorithm performs better than the recently reported methods without requiring any training data for a wide range of SNRs.